Let denote the matrix order (Loewner order). Most the following inequalities apply to more general linear operators.

As you’d expect, there are matrix versions of the Markov and Chebyshev inequalities. A good overview is given in Appendix C here: https://arxiv.org/pdf/quant-ph/0012127

For more sophisticated matrix inequalities (which often use the following inequalities in the background) see matrix inequalities.

Markov

For matrix and PSD ,

Of course, this reduces to usual Markov inequality (basic inequalities:Markov’s inequality).

Chebyshev

Markov’s inequality extends to Chebyshev’s inequality in the same way as in the scalar case:

A Chernoff-like inequality

For matrix , symmetric matrix and matrix such that where is the conjugate transpose of , we have

We can prove this easily using Markov’s inequality:

Here we’ve used that the exponential of the zero matrix is the identity. Note also that since the trace is a linear operator, so