Let denote the matrix order (Loewner order). Most the following inequalities apply to more general linear operators.
As you’d expect, there are matrix versions of the Markov and Chebyshev inequalities. A good overview is given in Appendix C here: https://arxiv.org/pdf/quant-ph/0012127
For more sophisticated matrix inequalities (which often use the following inequalities in the background) see matrix inequalities.
Markov
For matrix and PSD ,
Of course, this reduces to usual Markov inequality (basic inequalities:Markov’s inequality).
Chebyshev
Markov’s inequality extends to Chebyshev’s inequality in the same way as in the scalar case:
A Chernoff-like inequality
For matrix , symmetric matrix and matrix such that where is the conjugate transpose of , we have
We can prove this easily using Markov’s inequality:
Here we’ve used that the exponential of the zero matrix is the identity. Note also that since the trace is a linear operator, so